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- Morphological Control and Surface Modification Characteristics of Nickel Oxalate Synthesized via Oxalic Acid Precipitation
- Eunbi Park, Jongwon Bae, Sera Kang, Minsu Kang, Suseong Lee, Kun-Jae Lee
- J Powder Mater. 2025;32(5):375-382. Published online October 31, 2025
- DOI: https://doi.org/10.4150/jpm.2025.00248
- 666 View
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Abstract
PDF - Nickel is widely used in industrial fields such as electrocatalysis and energy storage devices. Although micron-sized nickel particles exhibit excellent mechanical durability, their low specific surface area limits their reactivity. We modified the surface of micron-sized nickel particles with nanostructured nickel oxalate and investigated the effects of the solvent dielectric constant, surfactant, and thermal treatment atmosphere on the resulting particle morphology and phase transformation. Rietveld refinement analysis confirmed that changes in the solvent dielectric constant led to increased or diminished crystallinity of specific planes in nickel oxalate, resulting in diffraction patterns distinct from standard JCPDS data. These structural changes were also found to influence the morphology of the synthesized nickel oxalate. The results demonstrate that nickel oxalate serves as an effective precursor for producing Ni and NiO phases, and shape control of the final product can increase the surface reactivity of micron-sized nickel materials.
- [English]
- Recovery of Barium, Nickel, and Titanium Powders from Waste MLCC
- Haein Shin, Kun-Jae Lee
- J Powder Mater. 2024;31(5):374-381. Published online October 31, 2024
- DOI: https://doi.org/10.4150/jpm.2024.00192
- 1,657 View
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Abstract
PDF
- The development of the electronics industry has led to an increased demand for the manufacture of MLCC (Multilayer Ceramic Capacitors), which in turn is expected to result in a rise in MLCC waste. The MLCC contains various metals, notably barium, titanium, and nickel, whose disposal is anticipated to increase correspondingly. Recently, recycling technologies for electronic waste have garnered attention as they address waste management and raw material supply challenges. This paper investigates the recovery of barium, nickel, and titanium from the MLCC by a hydrometallurgical process. Using citric acid, which is an organic acid, the metal inside the MLCC was leached. Additionally, metal materials were recovered through precipitation and complexing processes. As a result, barium and titanium were recovered from the leachate of the waste MLCC, and 93% of the nickel-based powder was recovered. Furthermore, the optimal recovery process conditions for recycling these metal elements were investigated.
- [Korean]
- Fabrication of Nanowire by Electrospinning Process Using Nickel Oxide Particle Recovered from MLCC
- Haein Shin, Jongwon Bae, Minsu Kang, Kun-Jae Lee
- J Powder Mater. 2023;30(6):502-508. Published online December 1, 2023
- DOI: https://doi.org/10.4150/KPMI.2023.30.6.502
- 568 View
- 13 Download
- 1 Citations
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Abstract
PDF
With the increasing demand for electronic products, the amount of multilayer ceramic capacitor (MLCC) waste has also increased. Recycling technology has recently gained attention because it can simultaneously address raw material supply and waste disposal issues. However, research on recovering valuable metals from MLCCs and converting the recovered metals into high-value-added materials remains insufficient. Herein, we describe an electrospinning (E-spinning) process to recover nickel from MLCCs and modulate the morphology of the recovered nickel oxide particles. The nickel oxalate powder was recovered using organic acid leaching and precipitation. Nickel oxide nanoparticles were prepared via heat treatment and ultrasonic milling. A mixture of nickel oxide particles and polyvinylpyrrolidone (PVP) was used as the E-spinning solution. A PVP/NiO nanowire composite was fabricated via Espinning, and a nickel oxide nanowire with a network structure was manufactured through calcination. The nanowire diameters and morphologies are discussed based on the nickel oxide content in the E-spinning solution.
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- Morphological Control and Surface Modification Characteristics of Nickel Oxalate Synthesized via Oxalic Acid Precipitation
Eunbi Park, Jongwon Bae, Sera Kang, Minsu Kang, Suseong Lee, Kun-Jae Lee
Journal of Powder Materials.2025; 32(5): 375. CrossRef
- Morphological Control and Surface Modification Characteristics of Nickel Oxalate Synthesized via Oxalic Acid Precipitation
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