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[Korean]
A Study of Various SiO2 Coating Control on White TiO2 Pigment for Cosmetic Applications
Minsol Park, Wooyoung Shim, YooJin Kim
J Powder Mater. 2022;29(3):207-212.   Published online June 1, 2022
DOI: https://doi.org/10.4150/KPMI.2022.29.3.207
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Nanosized rutile titanium dioxide (TiO2) is used in inorganic pigments and cosmetics because of its high whiteness and duality. The high quality of the white pigments depends on their surface coating technique via the solgel process. SiO2 coatings are required to improve the dispersibility, UV-blocking, and whiteness of TiO2. Tetraethyl orthosilicate (TEOS) is an important coating precursor owing to its ability to control various thicknesses and densities. In addition, we use Na2SiO3 (sodium silicate) as a precursor because of its low cost. Compared to TEOS, which controls the pH using a basic catalyst, Na2SiO3 controls the pH using an acid catalyst, giving a uniform coating. The coating thickness of TiO2 is controlled using a surface modifier, cetrimonium bromide, which is used in various applications. The shape and thickness of the nanosized coating layer on TiO2 are analyzed using transmission electron microscopy, and the SiO2 nanoparticle behavior in terms of the before-and-after size distribution is measured using a particle size analyzer. The color measurements of the SiO2 pigment are performed using UV-visible spectroscopy.

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[English]
Coating of Cobalt Over Tungsten Carbide Powder by Wet Chemical Reduction Method
Hyun-Seon Hong, Jin-Ho Yoon
J Korean Powder Metall Inst. 2014;21(2):93-96.   Published online April 1, 2014
DOI: https://doi.org/10.4150/KPMI.2014.21.2.93
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  • 3 Citations
AbstractAbstract PDF

Cobalt coated tungsten carbide-cobalt composite powder has been prepared through wet chemical reduction method. The cobalt sulfate solution was converted to the cobalt chloride then the cobalt hydroxide. The tungsten carbide powders were added in to the cobalt hydroxide, the cobalt hydroxide was reduced and coated over tungsten carbide powder using hypo-phosphorous acid. Both the cobalt and the tungsten carbide phase peaks were evident in the tungsten carbide-cobalt composite powder by X-ray diffraction. The average particle size measured via scanning electron microscope, particle size analysis was around 380 nm and the thickness of coated cobalt was determined to be 30~40 nm by transmission electron microscopy.

Citations

Citations to this article as recorded by  
  • Electroless Ni-P deposition on WC powders through direct PdCl2 activation and study on the underlying mechanisms
    Peng Tang, Shuwen Jiang, Jiawei Yan, Xianquan Li
    Next Materials.2025; 6: 100496.     CrossRef
  • Pre-treatments of initial materials for controlling synthesized TaC characteristics in the SHS process
    Jae Jin Sim, Sang Hoon Choi, Ji Hwan Park, Il Kyu Park, Jae Hong Lim, Kyoung Tae Park
    journal of Korean Powder Metallurgy Institute.2018; 25(3): 251.     CrossRef
  • Spark plasma sintering of WC–Co tool materials prepared with emphasis on WC core–Co shell structure development
    Sungkyu Lee, Hyun Seon Hong, Hyo-Seob Kim, Soon-Jik Hong, Jin-Ho Yoon
    International Journal of Refractory Metals and Hard Materials.2015; 53: 41.     CrossRef

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