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2 "Moon Sung Cho"
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[Korean]
Effect of Deposition Parameters on the Property of Silicon Carbide Layer in Coated Particle Nuclear Fuels
Yeon-Ku Kim, Weon-Ju Kim, SungHwan Yeo, Moon Sung Cho
J Korean Powder Metall Inst. 2016;23(5):384-390.   Published online October 1, 2016
DOI: https://doi.org/10.4150/KPMI.2016.23.5.384
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Tri-isotropic (TRISO) coatings on zirconia surrogate beads are deposited using a fluidized-bed vapor deposition (FB-CVD) method. The silicon carbide layer is particularly important among the coated layers because it acts as a miniature pressure vessel and a diffusion barrier to gaseous and metallic fission products in the TRISO-coated particles. In this study, we obtain a nearly stoichiometric composition in the SiC layer coated at 1400°C, 1500°C, and 1400°C with 20 vol.% methyltrichlorosilane (MTS), However, the composition of the SiC layer coated at 1300-1350°C shows a difference from the stoichiometric ratio (1:1). The density decreases remarkably with decreasing SiC deposition temperature because of the nanosized pores. The high density of the SiC layer (≥ 3.19 g/cm2) easily obtained at 1500°C and 1400°C with 20 vol.% MTS did not change at an annealing temperature of 1900°C, simulating the reactor operating temperature. The evaluation of the mechanical properties is limited because of the inaccurate values of hardness and Young’s modulus measured by the nano-indentation method.

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[Korean]
Characteristics of the Ammonium Diuranate Powders Prepared with Different Experimental Apparatus in Sol-gel Process
Yeon-Ku Kim, Kyung-Chai Jeong, Sung-Ho Ueom, Moon Sung Cho
J Korean Powder Metall Inst. 2012;19(6):398-404.
DOI: https://doi.org/10.4150/KPMI.2012.19.6.398
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This paper describes the spherical ammonium diuranate gel particles which are the intermediated material of the UO_2 microsphere for an VHTR(very high temperature reactor) nuclear fuel. The characteristics of the intermediate-ADU gel particles prepared by AWD(ageing, washing, and drying) and FB(fluidized-bed) apparatus were examined and compared in a sol-gel fabrication process. The electrical conductivity of washing filtrate from the FB treating and the surface area of dried-ADU gel particles were higher than those of AWD treating. Also, an internal pore volume in dried-ADU gel particles showed a more decrease in AWD treatment than FB treatment because of decomposition of PVA affected by the washing time. However, the internal microstructures of ADU gel particles were similar regardless of the process variation.

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