Tri-isotropic (TRISO) coatings on zirconia surrogate beads are deposited using a fluidized-bed vapor deposition (FB-CVD) method. The silicon carbide layer is particularly important among the coated layers because it acts as a miniature pressure vessel and a diffusion barrier to gaseous and metallic fission products in the TRISO-coated particles. In this study, we obtain a nearly stoichiometric composition in the SiC layer coated at 1400°C, 1500°C, and 1400°C with 20 vol.% methyltrichlorosilane (MTS), However, the composition of the SiC layer coated at 1300-1350°C shows a difference from the stoichiometric ratio (1:1). The density decreases remarkably with decreasing SiC deposition temperature because of the nanosized pores. The high density of the SiC layer (≥ 3.19 g/cm²) easily obtained at 1500°C and 1400°C with 20 vol.% MTS did not change at an annealing temperature of 1900°C, simulating the reactor operating temperature. The evaluation of the mechanical properties is limited because of the inaccurate values of hardness and Young’s modulus measured by the nano-indentation method.

Silicon carbide(SiC) layer is particularly important tri-isotropic (TRISO) coating layers because it acts as a miniature pressure vessel and a diffusion barrier to gaseous and metallic fission products in the TRISO coated particle. The high temperature deposition of SiC layer normally performed at 1500-1650°C has a negative effect on the property of IPyC layer by increasing its anisotropy. To investigate the feasibility of lower temperature SiC deposition, the influence of deposition temperature on the property of SiC layer are examined in this study. While the SiC layer coated at 1500°C obtains nearly stoichiometric composition, the composition of the SiC layer coated at 1300-1400°C shows discrepancy from stoichiometric ratio(1:1). 3-7 μm grain size of SiC layer coated at 1500°C is decreased to sub-micrometer (<1 μm) -2 μm grain size when coated at 1400°C, and further decreased to nano grain size when coated at 1300- 1350°C. Moreover, the high density of SiC layer (≥3.19 g/cm³) which is easily obtained at 1500°C coating is difficult to achieve at lower temperature owing to nano size pores. the density is remarkably decreased with decreasing SiC deposition temperature.

Citations

Citations to this article as recorded by  

• High-temperature thermo-mechanical behavior of functionally graded materials produced by plasma sprayed coating: Experimental and modeling results
  Kang Hyun Choi, Hyun-Su Kim, Chang Hyun Park, Gon-Ho Kim, Kyoung Ho Baik, Sung Ho Lee, Taehyung Kim, Hyoung Seop Kim
  Metals and Materials International.2016; 22(5): 817.     CrossRef

Citations

Citations to this article as recorded by  

• UO2 Spheres Produce by External Gelation Process
  Yeon-Ku Kim, Injin Sah, Eung Seon Kim
  Korean Journal of Materials Research.2020; 30(10): 533.     CrossRef
• Effects of Process Parameters on the Powder Characteristics of Uranium Oxide Kernel Prepared by Sol-gel Process
  Yeon-Ku Kim, Kyung-Chai Jeong, Seung-Chul Oh, Dong-Soo Suhr, Moon-Sung Cho
  Journal of Korean Powder Metallurgy Institute.2009; 16(4): 254.     CrossRef